Nickel supported on modified olivine catalysts for steam reforming of biomass gasification tar

Nickel supported on modified olivine catalysts for steam reforming of biomass gasification tar
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负载镍的改性橄榄石催化剂用于生物质气化焦油蒸汽重整

DOI:
10.1016/j.catcom.2009.11.006
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发表时间:
2010-01
影响因子:
3.7
通讯作者:
--
中科院分区:
化学3区
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--
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研制了镍改性橄榄石(Ni/MO)催化剂用于生物质气化焦油蒸汽重整。采用铝酸钙水泥对橄榄石粉末进行模压,然后煅烧制备改性橄榄石(MO)。采用湿浸渍法制备了Ni/MO催化剂。结果表明,Ni/MO催化剂的煅烧温度对其催化性能有显著影响。900℃煅烧的Ni/MO催化剂在苯蒸汽重整过程中表现出比传统Ni/橄榄石催化剂更高的活性和更强的抗结焦性。这一结果归因于MO的孔隙结构的改变和Ni-MO之间的适度相互作用。
Nickel-on-modified olivine (Ni/MO) catalysts were developed for tar steam reforming in biomass gasification. The modified olivine (MO) was prepared by moulding olivine powder with calcium aluminate cement followed by calcination. The Ni/MO catalysts were prepared by wet impregnation. It was found that calcination temperature of Ni/MO catalyst significantly influenced its catalytic behavior. The Ni/MO catalyst calcined at 900°C exhibited higher activity and better resistance to coking in steam reforming of benzene compared with the conventional Ni/olivine catalyst. This result was attributed to the modified pore structure of the MO and the moderate Ni–MO interaction.
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