Pseudopolyrotaxane composed of an azobenzene polymer and γ-cyclodextrin. Reversible and irreversible photoisomerization of the azobenzene groups in the polymer chain

Pseudopolyrotaxane composed of an azobenzene polymer and γ-cyclodextrin. Reversible and irreversible photoisomerization of the azobenzene groups in the polymer chain
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由偶氮苯聚合物和聚合物链中偶氮苯基团的可逆和不可逆光异构化组成的准聚轮烷。

DOI:
10.1039/b002642p
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发表时间:
2000
影响因子:
4.9
通讯作者:
Takakazu Yamamoto
Takakazu Yamamoto
中科院分区:
化学2区
文献类型:
--
作者:
I. Yamaguchi;K. Osakada;Takakazu Yamamoto

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一种由γ-环糊精和偶氮苯组成的聚轮烷 含有聚酯的聚酯经历UV光诱导的异构化, 反式-顺式-偶氮苯,而相反 异构化在通常的照射条件下不发生, 可见光
A polyrotaxane composed of γ-cyclodextrin and azobenzene containing polyester undergoes UV light induced isomerization of trans- to cis- azobenzene, whereas the reverse isomerization does not occur under the usual conditions of irradiation with visible light.