Synthesis of asymmetrically substituted 1,4,7,10-tetraazacyclododecanes for the triggered near infrared emission from lanthanide complexes.
Synthesis of asymmetrically substituted 1,4,7,10-tetraazacyclododecanes for the triggered near infrared emission from lanthanide complexes.
复制标题
合成不对称取代的 1,4,7,10-四氮杂环十二烷，用于触发稀土配合物的近红外发射。
作者：
K. Borbas;J. I. Bruce
开发了一种制备不对称取代的1,4,7,10-四氮杂十二烷衍生物的合成策略，以制备一系列基于Yb和Nd配合物的新型光活性供体-受体猝灭剂三联体；核苷猝灭剂用于调节供体和受体之间的能量转移程度。
A synthetic strategy to prepare asymmetrically substituted 1,4,7,10-tetrazadodecane derivatives was developed to prepare a novel series of photoactive donor-acceptor quencher triads based on Yb and Nd complexes; a nucleoside quencher is used to regulate the extent of energy transfer between the donor and the acceptor.