Carbometalation and Heterometalation of Carbon‐Carbon Multiple‐Bonds Using Group‐13 Heavy Metals: Carbogallation, Carboindation, Heterogallation, and Heteroindation
Carbometalation and Heterometalation of Carbon‐Carbon Multiple‐Bonds Using Group‐13 Heavy Metals: Carbogallation, Carboindation, Heterogallation, and Heteroindation
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使用第 13 族重金属的碳-碳多重键的碳金属化和杂金属化：碳镓化、碳结合、杂镓化和异质化
DOI：
10.1002/asia.201901730
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发表时间：
2020
期刊：
影响因子：
--
通讯作者：
Yasuda Makoto
中科院分区：
文献类型：
--
作者：
Nishimoto Yoshihiro;Yasuda Makoto
有机镓和铟化合物是有机合成中的有用试剂，因为它们具有中等的稳定性、有效的反应性和高的化学选择性。碳-碳多重键的碳配位和碳-碳键的结合实现了碳-碳键和碳-金属键的同时形成。杂原子和-indation构建碳-杂原子和碳-金属键。因此，这些反应体系代表了有机镓和铟的重要合成方法。许多化学家试图将各种类型的不饱和化合物如炔、烯和联烯应用于这些反应体系。本文简要综述了碳茚化和-griding以及异茚化和-griding。
Organogallium and ‐indium compounds are useful reagents in organic synthesis because of their moderate stability, efficient reactivity and high chemoselectivity. Carbogallation and ‐indation of a carbon‐carbon multiple bond achieves the simultaneous formation of carbon‐carbon and carbon‐metal bonds. Heterogallation and ‐indation construct carbon‐heteroatom and carbon‐metal bonds. Therefore, these reaction systems represent a significant synthetic method for organogalliums and ‐indiums. Many chemists have attempted to apply various types of unsaturated compounds such as alkynes, alkenes, and allenes to these reaction systems. This minireview provides an overview of carboindation and ‐gallation as well as heteroindation and ‐gallation.