Preparation and application of guanidyl-functionalized graphene oxide-grafted silica for efficient extraction of acidic herbicides by Box-Behnken design
Preparation and application of guanidyl-functionalized graphene oxide-grafted silica for efficient extraction of acidic herbicides by Box-Behnken design
复制标题
Box-Behnken设计胍基功能化氧化石墨烯接枝二氧化硅的制备及其在高效提取酸性除草剂中的应用
DOI：
10.1016/j.chroma.2018.08.030
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发表时间：
2018-10-12
影响因子：
4.1
通讯作者：
Guo, Yong
中科院分区：
文献类型：
--
作者：
Hou, Xiudan;Tang, Sheng;Guo, Yong
A highly selective and efficient extraction material was synthesized through the functionalization of guanidyl onto the graphene oxide-grafted silica via a simple chemical modification, which was designed and proposed to improve the enrichment capacity for acidic herbicides. The extraction material was confirmed by scanning electron microscopy, Fourier transform infrared spectrometry, X-ray photoelectron spectrometry, thermal gravimetric analyzer and zeta potential analysis. Theoretical adsorption energies, static- and dynamic-state binding experiments, and comparative experiments with various adsorbents were investigated to elucidate the adsorption mechanism. The introduction of guanidyl endowed the sorbent with stronger Lewis base property and electron-donating ability, hence, excellent extraction recoveries for acidic herbicides could be obtained. Besides, electrostatic and pi-pi interactions were considered as two major driving impetuses in the adsorption process. Single-factor experiment and response surface methodology were utilized for the optimization of extraction and desorption conditions. Under the optimized conditions, the wide linearities were obtained with correlation coefficients ranging from 0.9904 to 0.9980, and the method detection limits were in the range of 0.5-2 mu g L-1. The relative standard deviation values of the recoveries of five different extractions were 3.0-7.1%. Coupled with high performance liquid chromatography, the as-proposed method was successfully applied to detect five acidic herbicides in Lycium barbarum (Goji). It turned out that the proposed method provided a promising perspective for the selective extraction and determination of polar acidic compounds in complex samples. (C) 2018 Elsevier B.V. All rights reserved.
