Transition-Metal-Free Reaction of Aryltrimethylammonium Iodides with Arylzinc Reagents
Transition-Metal-Free Reaction of Aryltrimethylammonium Iodides with Arylzinc Reagents
复制标题
芳基三甲基碘化铵与芳基锌试剂的无过渡金属反应
DOI：
10.1002/asia.201701342
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
Wang Zhong-Xia
中科院分区：
文献类型：
--
作者：
Dai Wei-Can;Wang Zhong-Xia
在不存在过渡金属催化剂的情况下，芳基三甲基碘化铵与芳基氯化锌在温和条件下反应形成联芳基化合物。该反应适用于广泛的底物，并且表现出良好的官能团相容性。 Mg2+离子被证明可以显着促进反应。
Reaction of aryltrimethylammonium iodides with arylzinc chlorides in the absence of a transition-metal catalyst to form biaryl compounds was performed under mild conditions. The reaction was suitable for a broad scope of substrates and exhibited good compatibility of functional groups. The Mg2+ ion was demonstrated to markedly promote the reaction.