[Ru(phen)2dppz](2+) luminescence reveals nanoscale variation of polarity in the cyclodextrin cavity.
[Ru(phen)2dppz](2+) luminescence reveals nanoscale variation of polarity in the cyclodextrin cavity.
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DOI：
10.1039/c5cc09755j
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发表时间：
2016-01
影响因子：
4.9
通讯作者：
Patrick L. Higgs;A. W. McKinley;E. Tuite
中科院分区：
文献类型：
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作者：
Patrick L. Higgs;A. W. McKinley;E. Tuite
β-环糊精的磷酸化增强了与Ru（II）多吡啶络合物的结合，并基于手性和配体疏水性促进了选择性。对于[Ru（phen）2dppz]（2+），包含dppz会导致具有多个寿命的发光显着增加。地球物理学对环境的敏感响应揭示了纳米尺度的极性变化。
Phosphorylation of β-cyclodextrin enhances binding with Ru(II)polypyridyl complexes, and promotes selectivity based on chirality and ligand hydrophobicity. For [Ru(phen)2dppz](2+), inclusion of dppz results in a dramatic increase in luminescence with multiple lifetimes. The sensitive response of photophysics to the environment reveals nanoscale variation of polarity.