A Two-Directional Synthesis of (+)-ß-Isosparteine.
A Two-Directional Synthesis of (+)-ß-Isosparteine.
复制标题
( )-isosparteine 的双向合成。
DOI：
10.1021/acs.orglett.7b01475
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发表时间：
2017
期刊：
影响因子：
5.2
通讯作者：
Al-Saffar FM
中科院分区：
文献类型：
--
作者：
Al-Saffar FM
A two-directional synthesis of (+)-β-isosparteine is described in five steps from glutaric acid, where the entire carbon and nitrogen backbone of the alkaloid, possessing the requisite relative and absolute stereochemistry at its four stereogenic centers, is assembled using a double imino-aldol reaction.
