The first polyoxometalate-templated four-fold interpenetrated coordination polymer with new topology and ferroelectricity.
The first polyoxometalate-templated four-fold interpenetrated coordination polymer with new topology and ferroelectricity.
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DOI：
10.1039/b916462f
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发表时间：
2010-01
影响因子：
4
通讯作者：
Shoutian Zheng;Guo‐Yu Yang
中科院分区：
文献类型：
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作者：
Shoutian Zheng;Guo‐Yu Yang
将非协调的POMS作为模板的MOF很少见。我们报道了第一个四重互穿POM模板的3D MOF[Cu(3)(4，4‘-bpy)(5)](2)[H(2)SiW(11)O(39)]x5H(2)O，其骨架拓扑结构未知，顶点符号为(6×6×8(2))(2)(6×6×8×8×10(6)×10(6))。
MOFs including non-coordinating POMs as a template are rare. We report here the first four-fold interpenetrated POM-templated 3D MOF [Cu(3)(4,4'-bpy)(5)](2)[H(2)SiW(11)O(39)] x 5H(2)O, whose framework topology is previously unknown with the vertex symbol (6 x 6 x 8(2))(2)(6 x 6 x 8 x 8 x 10(6) x 10(6)).