NEW ANTIBIOTICS FROM FUNGUS EPICOCCUM-NIGRUM .2. EPICORAZINE-A - STRUCTURE ELUCIDATION AND ABSOLUTE-CONFIGURATION

NEW ANTIBIOTICS FROM FUNGUS EPICOCCUM-NIGRUM .2. EPICORAZINE-A - STRUCTURE ELUCIDATION AND ABSOLUTE-CONFIGURATION
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DOI:
10.7164/antibiotics.31.1102
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发表时间:
1978-01-01
影响因子:
3.3
通讯作者:
FILLEAU, MJ
FILLEAU, MJ
中科院分区:
医学4区
文献类型:
--
作者:
DEFFIEUX, G;BAUTE, MA;FILLEAU, MJ

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一种抗生素,epicorazine A,从一种特殊的真菌E.通过紫外光谱、红外光谱、质谱、核磁共振谱和圆二色性谱等分析,确定了一个新的环二硫二酮哌嗪。X射线衍射测量证实了这种结构及其绝对构型。
An antibiotic, epicorazine A, isolated from a particular strain of the fungus E. nigrum, was shown to be a new epidithiodiketopiperazine from its UV, IR, mass, NMR and CD [circular dichroism] spectra. X-Ray diffraction measures confirmed this structure and its absolute configuration.