Tuning the Reversibility of Mg Anodes via Controlled Surface Passivation by H2O/Cl- in Organic Electrolytes
Tuning the Reversibility of Mg Anodes via Controlled Surface Passivation by H2O/Cl- in Organic Electrolytes
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DOI：
10.1021/acs.chemmater.6b03227
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发表时间：
2016-11-22
影响因子：
8.6
通讯作者：
Markovic, Nenad M.
中科院分区：
文献类型：
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作者：
Connell, Justin G.;Genorio, Bostjan;Markovic, Nenad M.
开发新一代电池化学材料是超越当前锂离子技术的关键挑战。在这项工作中，我们介绍了一种基于表面科学的方法，用于理解控制镁离子电池镁阳极可逆性的复杂现象。我们确定了痕量 H2O 水平的深远影响（
Developing a new generation of battery chemistries is a critical challenge to moving beyond current Li-ion technologies. In this work, we introduce a surface science-based approach for understanding the complex phenomena controlling the reversibility of Mg anodes for Mg-ion batteries. We identify the profound impact of trace levels of H2O (