Highly enantioselective synthesis of tetrahydro-β-carbolines and tetrahydro-γ-carbolines via Pd-catalyzed intramolecular allylic alkylation
Highly enantioselective synthesis of tetrahydro-β-carbolines and tetrahydro-γ-carbolines via Pd-catalyzed intramolecular allylic alkylation
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DOI：
10.1021/ja054109o
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发表时间：
2006-02-08
影响因子：
15
通讯作者：
Umani-Ronchi, A
中科院分区：
文献类型：
--
作者：
Bandini, M;Melloni, A;Umani-Ronchi, A
一种新的钯催化吲哚的分子内烯丙基烷基化反应允许有效地合成THBCs和THGC，产率高，对映体过量（ee高达97%）。
A novel Pd-catalyzed intramolecular allylic alkylation of indoles allows THBCs and THGCs to be effectively synthesized in high yields and excellent enantiomeric excesses (ee up to 97%).