Palladium catalyzed dual C-H functionalization of indoles with cyclic diaryliodoniums, an approach to ring fused carbazole derivatives.
Palladium catalyzed dual C-H functionalization of indoles with cyclic diaryliodoniums, an approach to ring fused carbazole derivatives.
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DOI：
10.1039/c4ob02170c
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发表时间：
2014-11
影响因子：
3.2
通讯作者：
Yongcheng Wu;X. Peng;Bingling Luo;Fuhai Wu;Bo Liu;F. Song;Peng-mian Huang;S. Wen
中科院分区：
文献类型：
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作者：
Yongcheng Wu;X. Peng;Bingling Luo;Fuhai Wu;Bo Liu;F. Song;Peng-mian Huang;S. Wen
成功地实现了钯(II)催化的吲哚与环状二芳基碘的双C-H官能化反应，为合成二苯并咔唑提供了一种简便的方法。在一次操作中，形成了两个C-C键和一个环。该反应是无配体的，耐受空气和潮湿的条件。
Palladium(II)-catalyzed dual C-H functionalization of indoles with cyclic diaryliodoniums was successfully achieved, providing a concise method to synthesize dibenzocarbazoles. In a single operation, two C-C bonds and one ring were formed. The reaction was ligand free and tolerated air and moisture conditions.