The synthesis and chemistry of icosahedral bis(phosphine)metalladiarsaboranes and -distibaboranes containing nickel and palladium. Crystal and molecular structures of closo-1,1-(Me2PPh)2-1,2,3-PdAs2B9H9, closo-1,6-Cl2-1,5-(Me2PPh)2-1,2,3-PdAs2B9H7.CH2Cl2, and closo-1,1-(Me2PPh)2-1,2,3-PdSb2B9H9
The synthesis and chemistry of icosahedral bis(phosphine)metalladiarsaboranes and -distibaboranes containing nickel and palladium. Crystal and molecular structures of closo-1,1-(Me2PPh)2-1,2,3-PdAs2B9H9, closo-1,6-Cl2-1,5-(Me2PPh)2-1,2,3-PdAs2B9H7.CH2Cl2, and closo-1,1-(Me2PPh)2-1,2,3-PdSb2B9H9
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含镍和钯的二十面体双(膦)金属二硼硼烷和二二硼硼烷的合成和化学。
DOI：
10.1021/ic00066a018
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发表时间：
1993
影响因子：
4.6
通讯作者：
L. J. Todd
中科院分区：
文献类型：
--
作者：
S. A. Jasper;Steven L. Roach;John N. Stipp;J. Huffman;L. J. Todd
在室温下，（me2pph） 2mcl 2 （M=Ni或Pd）与nido7,8 - as2b9h92 -离子反应，（me2pph） 2pdcl 2与nido7,8 - s2b9h92 -离子反应，形成了二十面体双（磷化氢）金属二异硼烷，M=Ni（As为1）或M=Pd （As为3，Sb为5）产率为中低。
The reaction of (Me 2 PPh) 2 MCl 2 species (M=Ni or Pd) with the nido-7,8-As 2 B 9 H 9 2- ion and (Me 2 PPh) 2 PdCl 2 with the nido-7,8-Sb 2 B 9 H 9 2- ion at room temperature led to the formation of icosahedral bis(phosphine)metalladiheteroboranes in low to moderate yields for M=Ni(1 for As) or M=Pd (3 for As and 5 for Sb)