The influence of imperfect walls on the guest binding properties of hydrogen-bonded capsules.
The influence of imperfect walls on the guest binding properties of hydrogen-bonded capsules.
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DOI：
10.1039/c5cc06727h
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发表时间：
2015-10
影响因子：
4.9
通讯作者：
Changbao Zhu;Haoyu Wang;Jiao-Nan Sun;G. Ye;J. Rebek;Wei‐Qun Jiang
中科院分区：
文献类型：
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作者：
Changbao Zhu;Haoyu Wang;Jiao-Nan Sun;G. Ye;J. Rebek;Wei‐Qun Jiang
制备了三类具有不完整壁的氢键胶囊并进行了表征。这些缺陷降低了胶囊的对称性，导致丰富的异构性。缺失的氢键为胶囊提供了额外的灵活性，并对它们在不同组装体中的客体结合性质产生影响。
Three classes of hydrogen-bonded capsules with imperfect walls have been prepared and characterized. The defects reduce the symmetry of the capsules, leading to rich isomerism. The missing hydrogen bonds provide additional flexibility to the capsules and exert an influence on their guest binding properties in different assemblies.