Phosphorylation of p-tert-butylthiacalix[4]arene: reaction with phosphorous triamides
Phosphorylation of p-tert-butylthiacalix[4]arene: reaction with phosphorous triamides
复制标题
对叔丁基硫杂[4]芳烃的磷酸化：与三酰胺磷的反应
DOI：
10.1039/b000465k
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发表时间：
2000
期刊：
影响因子：
--
通讯作者：
W. Habicher
中科院分区：
文献类型：
--
作者：
D. Weber;M. Gruner;I. Stoikov;I. Antipin;W. Habicher
对叔丁基硫杂杯[4]芳烃1与PCl 3反应生成氯化亚磷双酯2，后者可转化为双环亚磷双酯酰胺3。该衍生物的构象被发现是1，2-交替与两个不同磁性的磷原子。1与P（NEt 2）3反应得到不对称磷硫杂杯[4]芳烃4。用核磁共振方法确定了磷硫杂杯[4]芳烃3和4的构象。在−80 °C至+120 °C的温度范围内，通过随温度变化的1H NMR和31 P NMR光谱研究了磷硫杂杯芳烃3。在此范围内，未检测到构象变化。化合物3中的磷原子由于所处环境的不同，在过氧化氢异丙苯的氧化实验中表现出不同的反应活性。
The reaction of p-tert-butylthiacalix[4]arene 1 with PCl3 gives the phosphorous diester chloride 2 which could be transformed into the double cyclic phosphorous diester amide 3. The conformation of this derivative was found to be 1,2-alternate with two magnetically different phosphorus atoms. The reaction of 1 with P(NEt2)3 gives the asymmetric phosphorus thiacalix[4]arene 4. The conformations of the phosphorus thiacalix[4]arenes 3 and 4 were determined by NMR methods. Phosphorus thiacalixarene 3 was investigated by temperature-dependent 1H NMR and 31P NMR spectroscopy in a range from −80 °C to +120 °C. In this range, no conformational changes could be detected. Due to their different environments, the phosphorus atoms in compound 3 show different reactivities in oxidation experiments with cumene hydroperoxide.
影响因子：
4
作者：
Iki, N;Morohashi, N;Miyano, S
通讯作者：
Miyano, S