Glochidionolactones A-F: butenolide glucosides from leaves of Glochidion zeylanicum (GAERTN) A. JUSS.

Glochidionolactones A-F: butenolide glucosides from leaves of Glochidion zeylanicum (GAERTN) A. JUSS.
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DOI:
10.1248/cpb.48.547
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发表时间:
2000-04
影响因子:
1.7
通讯作者:
H. Otsuka;E. Hirata;A. Takushi;T. Shinzato;Y. Takeda;M. Bando;M. Kido
H. Otsuka;E. Hirata;A. Takushi;T. Shinzato;Y. Takeda;M. Bando;M. Kido
中科院分区:
医学4区
文献类型:
--
作者:
H. Otsuka;E. Hirata;A. Takushi;T. Shinzato;Y. Takeda;M. Bando;M. Kido

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从锡兰算盘子(Glochidion zeylanicum)叶中分得6个新的丁烯二醇葡萄糖苷,命名为算盘子内酯(glochidionolactones)A-F,同时沿着一个已知的相关化合物叶绿酸内酯(phylanthurinolactone)。通过波谱分析鉴定了其中的化合物A ~ D和F的结构。通过X-射线晶体学分析确定了钩虫内酯E的绝对立体化学结构。
From the leaves of Glochidion zeylanicum, six new butenolide glucoside, named glochidionolactones A-F, were isolated along with a known related compound, phyllanthurinolactone. The structures of glochidionolactones A-D and F were elucidated mainly by spectroscopic analyses. The absolute stereochemistry of glochidionolactone E was established by X-ray crystallographic analysis.