Sapphyrins: versatile anion binding agents.
Sapphyrins: versatile anion binding agents.
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DOI：
10.1021/ar980117g
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发表时间：
2001-11
影响因子：
18.3
通讯作者：
J. Sessler;Julian M. Davis
中科院分区：
文献类型：
--
作者：
J. Sessler;Julian M. Davis
蓝宝石是文献中报道的第一个扩展的卟啉，并且仍然是研究最广泛的之一。对这种大环的兴趣很大程度上反映了它结合阴离子的能力，这种现象已通过广泛的实验技术在溶液和固态中进行了检查。在本报告中，我们总结了这些研究，同时概述了可用于合成蓝宝石的策略。
Sapphyrin was the first expanded porphyrin to be reported in the literature and remains among the most extensively studied. Much of the interest in this macrocycle reflects its ability to bind anions, a phenomenon that has been examined in solution and in the solid state by a wide range of experimental techniques. In this Account, we summarize these studies while also outlining strategies that may be used to synthesize sapphyrins.