Disambiguation of Metal and Bronsted Acid Catalyzed Pathways for Hydroarylation with Platinum(II) Catalysts
Disambiguation of Metal and Bronsted Acid Catalyzed Pathways for Hydroarylation with Platinum(II) Catalysts
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DOI：
10.1021/om2000458
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发表时间：
2011-03-28
期刊：
影响因子：
2.8
通讯作者：
Tilley, T. Don
中科院分区：
文献类型：
--
作者：
Bowring, Miriam A.;Bergman, Robert G.;Tilley, T. Don
在Pt（II）预催化剂的作用下，未活化烯烃的氢化芳基化反应通过原位生成proproacid进行，并遵循Friedel Crafts机制。采用阻碍碱2,6-二叔丁基-4-甲基吡啶和多种底物研究了该反应。
The hydroarylation of unactivated olefins effected by Pt(II) precatalysts was found to proceed through the in situ production of protic acid followed by a Friedel Crafts mechanism. The reaction was investigated using the hindered base 2,6-di-tert-butyl-4-methylpyridine and a variety of substrates.