Novel photofunctional hybrid materials (alumina and titania) functionalized with both MOF and lanthanide complexes through coordination bonds
Novel photofunctional hybrid materials (alumina and titania) functionalized with both MOF and lanthanide complexes through coordination bonds
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通过配位键与 MOF 和镧系元素配合物进行功能化的新型光功能杂化材料（氧化铝和二氧化钛）
DOI：
10.1039/c4ra05704j
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发表时间：
2014-08
期刊：
影响因子：
3.9
通讯作者：
Yan, Bing
中科院分区：
文献类型：
--
作者：
Xu, Xiao-Yu;Yan, Bing
In this paper, series of luminescent hybrid materials (alumina, titania) functionalized with both lanthanide complexes and metal organic frameworks (MOF, Al-MIL-53-COOH) through coordination bonds. In these hybrid systems, both MOF and lanthanide (Eu3+, Tb3+) complexes with beta-diketonates (2-thenoyltrifluoroacetonate (TTA), 1,1,1-trifluoroacetylacetone (TAA), 2,4-pentanedionate (AA)) and pyridine-3,5-dicarboxylic acid (PDA) are coordinated to alumina and titania through their carboxylic groups. Al-MIL-53-COOH possesses the active –COOH group and can be linked to metallic alkoxides (Ti[OCH(CH3)2]4 and Al[OCH(CH3)2]3), by a post-synthesis path. Ternary complexes of beta-diketonates and PDA can be further bonded with metallic alkoxides through PDA as a bridge for its carboxylic group coordination. After hydrolysis and a condensation process, the final multi-component hybrid materials can be assembled and characterized. The photophysical properties of these hybrid materials were studied in detail, and their luminescent color can be tuned by controlling the composition of different units in the hybrid system. Especially with the hybrids of europium complexes and MOF, the white luminescence can be obtained by integrating the emission of both europium complex and MOF. Furthermore, the luminescent films that were prepared show both uniformity and transparency. These results provide some useful data for the multi-component assembly and luminescent integration of photofunctional hybrid materials based on MOF and lanthanide units, which can be expected to have some potential applications in luminescent devices for display or lighting.
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影响因子：
5.2
作者：
Meng, QG;Boutinaud, P;Mahiou, R
通讯作者：
Mahiou, R
功能性噻唑桥的镧系元素杂化物的化学键组装、物理表征和光物理性质
影响因子：
2.3
作者：
Guo, Lei;Yan, Bing
通讯作者：
Yan, Bing
DOI：
10.1021/jp044591h
发表时间：
2005-03
期刊：
The journal of physical chemistry. B
影响因子：
--
作者：
Lining Sun;Hong‐Jie Zhang;Q. Meng;Feng-yi Liu;L. Fu;Chunyun Peng;Jiangbo Yu;G. Zheng;Shu-bin Wan
通讯作者：
Lining Sun;Hong‐Jie Zhang;Q. Meng;Feng-yi Liu;L. Fu;Chunyun Peng;Jiangbo Yu;G. Zheng;Shu-bin Wan
基于2-硫酰基吡啶-3-羧酸和二氧化硅/二氧化钛基质的多功能配合物的新型镧系元素发光材料
影响因子：
--
作者：
Guo, Lei;Fu, Lianshe;Ferreira, Rute A. S.;Carlos, Luis D.;Li, Qiuping;Yan, Bing
通讯作者：
Yan, Bing
DOI：
10.1021/jp073531j
发表时间：
2007-10
期刊：
The journal of physical chemistry. B
影响因子：
--
作者：
B. Yan;Xiaofei Qiao
通讯作者：
B. Yan;Xiaofei Qiao