Scaling Laws in Supramolecular Polymer Networks.

Scaling Laws in Supramolecular Polymer Networks.
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DOI:
10.1021/ma200096s
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发表时间:
2011
期刊:
影响因子:
5.5
通讯作者:
Craig SL
Craig SL
中科院分区:
化学1区
文献类型:
--
作者:
Xu D;Craig SL

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研究了在聚4-乙烯基吡啶(PVP)溶液中加入双Pd(II)交联剂形成的网络的线性流变性能,确定了网络的零剪切粘度(η0)与PVP溶液浓度(CPVP)、交联剂浓度(CX)和弹性活性链数密度(vphantom)之间的标度律关系。将标度律关系与Sticky Rouse和Sticky Reptation模型(Macromolecules 2001,34,1058-1068)的理论预期进行比较,并且观察到定性和定量差异。
The linear rheological properties of networks formed by adding bis-Pd(II) cross-linkers to poly(4-vinylpyridine) (PVP) solution are examined, and the scaling law relationships between the zero shear viscosity (η0) of the networks versus the concentration of PVP solution (CPVP), the concentration of cross-linkers (CX), and the number density of elastically active chains (vphantom) are experimentally determined. The scaling law relationships are compared to the theoretical expectations of the Sticky Rouse and Sticky Reptation models (Macromolecules 2001, 34, 1058-1068), and both qualitative and quantitative differences are observed.
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