Scaling Laws in Supramolecular Polymer Networks.
Scaling Laws in Supramolecular Polymer Networks.
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DOI:
10.1021/ma200096s
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发表时间:
2011
期刊:
影响因子:
5.5
通讯作者:
Craig SL
中科院分区:
文献类型:
--
作者:
Xu D;Craig SL
The linear rheological properties of networks formed by adding bis-Pd(II) cross-linkers to poly(4-vinylpyridine) (PVP) solution are examined, and the scaling law relationships between the zero shear viscosity (η0) of the networks versus the concentration of PVP solution (CPVP), the concentration of cross-linkers (CX), and the number density of elastically active chains (vphantom) are experimentally determined. The scaling law relationships are compared to the theoretical expectations of the Sticky Rouse and Sticky Reptation models (Macromolecules 2001, 34, 1058-1068), and both qualitative and quantitative differences are observed.
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