Using metallo-supramolecular block copolymers for the synthesis of higher order nanostructured assemblies.
Using metallo-supramolecular block copolymers for the synthesis of higher order nanostructured assemblies.
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DOI：
10.1002/marc.200900496
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发表时间：
2010-01
影响因子：
4.6
通讯作者：
Adam O. Moughton;R. O’Reilly
中科院分区：
文献类型：
--
作者：
Adam O. Moughton;R. O’Reilly
许多研究小组探索了主链金属超分子多嵌段共聚物的性能和溶液自组装。直到最近，这些金属配合物主要用于制备胶束型结构。然而，此类共聚物的自组装已被进一步开发以创建更先进的结构，这些结构利用其结构单元的可逆超分子连接作为其合成中的关键成分。此外，将多重正交相互作用和刺激响应聚合物纳入其设计中，可以更精确地对其性能进行外部控制。这篇专题文章讨论了最新的进展，并深入探讨了它们在创建新颖、智能和响应性纳米结构方面的潜在开发和开发。
Many research groups have explored the properties and solution self-assembly of main chain metallo-supramolecular multiblock copolymers. Until recently, these metal complexes have been used to prepare mainly micelle type structures. However, the self-assembly of such copolymers has been exploited further to create more advanced architectures which utilize the reversible supramolecular linkage of their building blocks as a key component in their synthesis. Furthermore, the incorporation of multiple orthogonal interactions and stimuli responsive polymers into their design, enables more precise external control of their properties. This feature article discusses recent developments and provides an insight into their potential exploitation and development for the creation of novel, smart, and responsive nanostructures.