Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction
Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO2 reduction
复制标题
具有 PNNP 四齿配体的铱光催化剂的空间体积对于 CO2 还原的重要性
DOI：
10.1039/d2cc01701f
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发表时间：
2022
影响因子：
4.9
通讯作者：
Saito Susumu
中科院分区：
文献类型：
--
作者：
Kamada Kenji;Jung Jieun;Kametani Yohei;Wakabayashi Taku;Shiota Yoshihito;Yoshizawa Kazunari;Bae Seong Hee;Muraki Manami;Naruto Masayuki;Sekizawa Keita;Sato Shunsuke;Morikawa Takeshi;Saito Susumu
一系列 Ir 配合物已被开发为多功能光催化剂，用于 CO2 还原，选择性地产生 HCO2H。该系列的催化活性和光物理性质差异很大，大基团插入导致形成HCO2H和CO，催化剂周转数>10 400。
A series of Ir complexes has been developed as multifunctional photocatalysts for CO2 reduction to give HCO2H selectively. The catalytic activities and photophysical properties vary widely across the series, and the bulky group insertion resulted in the formation of HCO2H and CO with the catalyst turnover number of >10 400.