Hydrogen Self-Sufficient Arene Reduction to Cyclohexane Derivatives Using a Combination of Platinum on Carbon and 2-Propanol
Hydrogen Self-Sufficient Arene Reduction to Cyclohexane Derivatives Using a Combination of Platinum on Carbon and 2-Propanol
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DOI：
10.1002/adsc.201500263
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发表时间：
2015-09
影响因子：
5.4
通讯作者：
Y. Sawama;Misato Mori;Tsuyoshi Yamada;Y. Monguchi;H. Sajiki
中科院分区：
文献类型：
--
作者：
Y. Sawama;Misato Mori;Tsuyoshi Yamada;Y. Monguchi;H. Sajiki
在异丙醇-水混合溶剂中，在100 °C下，在不添加可燃性氢气的情况下，使用碳载铂氢化各种芳烃，得到相应的环己烷衍生物。2-丙醇在铂碳催化脱氢反应中作为一种有效的氢源发挥作用。
Various arenes have been hydrogenated using platinum on carbon in a 2-propanol-aqueous mixed solvent at 100 °C without the addition of flammable hydrogen gas to give the corresponding cyclohexane derivatives. 2-Propanol plays a role as an efficient hydrogen source based on the platinum on carbon-catalyzed dehydrogenation.