Synthesis and Complexation of a New Tripodal Tetradentate Ligand, a Silyl Ligand Tethered with Three Thioether Moieties
Synthesis and Complexation of a New Tripodal Tetradentate Ligand, a Silyl Ligand Tethered with Three Thioether Moieties
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DOI：
10.1021/om100255p
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发表时间：
2010-06
期刊：
影响因子：
2.8
通讯作者：
N. Takeda;D. Watanabe;Tetsu Nakamura;M. Unno
中科院分区：
文献类型：
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作者：
N. Takeda;D. Watanabe;Tetsu Nakamura;M. Unno
合成了铱（III）、铂（II）与三[2-（叔丁基硫代甲基）苯基]硅基三脚架四齿配体的配合物。此外，三（2-（（叔丁基硫基）甲基）苯基）硅烷与[PdCl 2（PhCN）2]反应导致Si-C键断裂，得到[{Pd[2-（t-BuSCH 2）C6 H4]}2（μ-Cl）2]。
Iridium(III) and platinum(II) complexes with a new tripodal tetradentate ligand, tris[2-(tert-butylthiomethyl)phenyl]silyl were synthesized. In addition, reaction of tris(2-((tert-butylthio)methyl)phenyl)silane with [PdCl2(PhCN)2] resulted in the cleavage of the Si−C bond to give [{Pd[2-(t-BuSCH2)C6H4]}2(μ-Cl)2].