The first [2]cobaltocenophane and [2]metallocenophanium salts

The first [2]cobaltocenophane and [2]metallocenophanium salts
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第一个[2]钴茂盐和[2]金属茂盐

DOI:
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发表时间:
1996
期刊:
影响因子:
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通讯作者:
I. Manners
I. Manners
中科院分区:
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文献类型:
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作者:
Mark J. Drewitt;S. Barlow;D. O′Hare;J. Nelson;P. Nguyen;I. Manners

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由2-叔丁基-6,6-二甲基芴经两步合成了四甲基乙烯桥连的二茂铁1和二茂钴3。两者都可以被氧化成相应的阳离子,2和4,其单晶X射线结构已被确定。
A tetramethylethylene bridged ferrocene 1 and cobaltocene 3 are synthesised in two steps from 2-tert-butyl-6,6-dimethylfluvene. Both can be oxidised to the corresponding cations, 2 and 4, the single-crystal X-ray structures of which have been determined.