A selective palladium-catalyzed carbonylative arylation of aryl ketones to give vinylbenzoate compounds.

A selective palladium-catalyzed carbonylative arylation of aryl ketones to give vinylbenzoate compounds.
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DOI：
10.1002/chem.201202895
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发表时间：
2012-12
期刊：
Chemistry
影响因子：
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通讯作者：
Johannes Schranck;A. Tlili;H. Neumann;P. Alsabeh;M. Stradiotto;M. Beller
Johannes Schranck;A. Tlili;H. Neumann;P. Alsabeh;M. Stradiotto;M. Beller
中科院分区：
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文献类型：
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作者：
Johannes Schranck;A. Tlili;H. Neumann;P. Alsabeh;M. Stradiotto;M. Beller

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烯醇的制备：在CO气氛下，用[{Pd（cinnamyl）Cl}（2）]/催化剂A（nBuPAd（2），Ad=金刚烷基）处理芳基酮，芳基酮与芳基卤发生羰基化C-O偶联反应，生成（Z）-苯甲酸乙烯酯。
Preparation of enols: when treated with [{Pd(cinnamyl)Cl}(2)]/cataCXium A (nBuPAd(2), Ad=adamantyl) under an atmosphere of CO, aryl ketones react with aryl halides in a carbonylative C-O coupling reaction to form (Z)-vinyl benzoates.