A cryostat for low temperature resonance Raman measurements on operando oxygenated bioinorganic model complexes
A cryostat for low temperature resonance Raman measurements on operando oxygenated bioinorganic model complexes
复制标题
用于对操作含氧生物无机模型复合物进行低温共振拉曼测量的低温恒温器
DOI:
10.1016/j.ica.2017.07.010
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发表时间:
2017
影响因子:
2.8
通讯作者:
M. Rübhausen
中科院分区:
文献类型:
--
作者:
B. Grimm-Lebsanft;C. Brett;F. Strassl;D. Rukser;M. Biednov;F. Biebl;M. Naumova;A. Hoffmann;L. Akinsinde;D. Brückner;S. Herres-Pawlis;M. Rübhausen
Raman spectroscopy is a useful tool for the elucidation of bioinorganic mechanisms. To investigate charge-transfer processes inoperandooxygenated bioinorganic samples, we present a new cryostat for liquid samples at low temperature. We reach temperatures below −80 °C inside a Suprasil glass cuvette which is prerequisite for the formation of the oxo species and long-term stability of the sample. Underoperandoconditions we demonstrate resonance Raman as well as isotope substitution measurements on a bis(μ-oxo) dicopper(III) complex. Future applications of our setup are envisioned to be transient Raman, steady-state and time-resolved fluorescence as well as transient absorption spectroscopy of bioinorganic or other charge-transfer complexes.
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DOI:
--
发表时间:
2016
期刊:
影响因子:
--
作者:
Daniela Schurr;Florian Strassl;Patricia Liebhäuser;G. Rinke;R. Dittmeyer;S. Herres‐Pawlis
通讯作者:
S. Herres‐Pawlis
影响因子:
62.1
作者:
Elwell CE;Gagnon NL;Neisen BD;Dhar D;Spaeth AD;Yee GM;Tolman WB
通讯作者:
Tolman WB
DOI:
10.1016/b978-0-12-409547-2.11554-9
发表时间:
2017
期刊:
Reference Module in Chemistry, Molecular Sciences and Chemical Engineering
影响因子:
--
作者:
P. Liebhäuser;A. Hoffmann;S. Herres-Pawlis
通讯作者:
S. Herres-Pawlis
DOI:
--
发表时间:
1997
期刊:
影响因子:
--
作者:
V. Mahadevan;Zhiguo Hou;Adam P. Cole;D. Root;T. K. Lal;E. Solomon;T. Stack
通讯作者:
T. Stack
DOI:
--
发表时间:
2004
期刊:
Bull. Chem. Soc. Jpn 77
影响因子:
--
作者:
Komiyama;K.
通讯作者:
K.