A cryostat for low temperature resonance Raman measurements on operando oxygenated bioinorganic model complexes

A cryostat for low temperature resonance Raman measurements on operando oxygenated bioinorganic model complexes
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用于对操作含氧生物无机模型复合物进行低温共振拉曼测量的低温恒温器

DOI:
10.1016/j.ica.2017.07.010
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发表时间:
2017
影响因子:
2.8
通讯作者:
M. Rübhausen
M. Rübhausen
中科院分区:
化学3区
文献类型:
--
作者:
B. Grimm-Lebsanft;C. Brett;F. Strassl;D. Rukser;M. Biednov;F. Biebl;M. Naumova;A. Hoffmann;L. Akinsinde;D. Brückner;S. Herres-Pawlis;M. Rübhausen

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Raman spectroscopy is a useful tool for the elucidation of bioinorganic mechanisms. To investigate charge-transfer processes inoperandooxygenated bioinorganic samples, we present a new cryostat for liquid samples at low temperature. We reach temperatures below −80 °C inside a Suprasil glass cuvette which is prerequisite for the formation of the oxo species and long-term stability of the sample. Underoperandoconditions we demonstrate resonance Raman as well as isotope substitution measurements on a bis(μ-oxo) dicopper(III) complex. Future applications of our setup are envisioned to be transient Raman, steady-state and time-resolved fluorescence as well as transient absorption spectroscopy of bioinorganic or other charge-transfer complexes.
环境条件下 SuperFocus 混合器中敏感生物无机物质的衰变动力学
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