Investigations of small carbon cluster-ion structures by reactions with hydrogen cyanide

Investigations of small carbon cluster-ion structures by reactions with hydrogen cyanide
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通过与氰化氢反应研究小碳簇离子结构

DOI：
10.1021/ja00189a004
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发表时间：
1989
期刊：
影响因子：
--
通讯作者：
S. Mcelvany
S. Mcelvany
中科院分区：
--
文献类型：
--
作者：
D. C. Parent;S. Mcelvany

文献摘要

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结论Fe+-苯胺具有有趣的反应活性。铁离子通过脱氢氯化反应可诱导氯苯聚合生成铁离子聚苯或CC插入聚苯。形成铁+-六苯乙烯的反应比前面的步骤要慢得多。对Fe+-聚苯乙烯的碰撞离解表明，在7.870 eV时，双苯基、三苯基和四苯基的电离势都低于Fe。
ConclusionInteresting reactivity is observed for Fe+-benzyne. Fe+ can induce polymerizationof chlorobenzene to form Fe+-poly-phenylene or CC inserted polyphenylene via dehydrochlorination up to the sixth step. The reaction to form Fe+-hexaphenylene is significantly slower than the earlier steps. Collision-induced dissociation on Fe+-polyphenylene suggests that bisphenylene, trisphenylene, and tetraphenylene all have ionization potentials lower than that of Fe at 7.870 eV.