Superspace crystallography: a key to the chemistry and properties.

Superspace crystallography: a key to the chemistry and properties.
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DOI:
10.1107/s2052252514023550
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发表时间:
2015-01-01
期刊:
影响因子:
3.9
通讯作者:
Abakumov AM
Abakumov AM
中科院分区:
材料科学2区
文献类型:
--
作者:
Pinheiro CB;Abakumov AM

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综述了调制分子和无机晶体领域的最新进展。概述了详细的调制结构知识对理解晶体化学和调制相的功能性质的重要性。综述了调制分子和无机晶体领域的最新进展,重点介绍了不可公度性、分子间和原子间相互作用之间的联系,以及可能的情况下材料的性质。通过选择有机分子化合物和无机复合氧化物中的无公度调制的例子,说明了详细的调制结构知识对于理解晶体化学和调制相的功能性质的重要性。
An overview is given to recent advances in the field of modulated molecular and inorganic crystals. The importance of detailed knowledge of the modulated structure to understand crystal chemistry and the functional properties of the modulated phases is outlined. An overview is given of the recent advances in the field of modulated molecular and inorganic crystals with an emphasis on the links between incommensurability, intermolecular and interatomic interactions and, wherever possible, the properties of the materials. The importance of detailed knowledge on the modulated structure for understanding the crystal chemistry and the functional properties of modulated phases is shown using selected examples of incommensurate modulations in organic molecular compounds and inorganic complex oxides.