Chemical analysis of thin black layers on building stone

Chemical analysis of thin black layers on building stone
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建筑石材上黑色薄层的化学分析

DOI:
10.1179/sic.1993.38.1.25
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发表时间:
1993
影响因子:
0.8
通讯作者:
T. Ericsson
T. Ericsson
中科院分区:
化学4区
文献类型:
--
作者:
A. Nord;T. Ericsson

文献摘要

被引文献

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污染地区的建筑石材常出现黑色薄层。各种技术,包括扫描电子显微镜/能量色散X射线照相术,电子能谱化学分析,穆斯堡尔谱和气相色谱-质谱法已被用来分析这些层的样品来自瑞典和其他一些欧洲国家。这些层主要由各种氧化铁和氧化铁氢氧化物、硫酸盐、烟灰和硅酸盐矿物组成,含有少量的金属、橡胶和沥青颗粒,以及许多低浓度的有机成分。空气污染物和某种程度上来自石头内部的矿物质是形成黑色层的成分的主要来源。
AbstractThin black layers often occur on building stone in polluted areas. Various techniques including scanning electron microscopy/energy dispersive X-radiography, electron spectroscopy for chemical analysis, Mossbauer spectroscopy and gas chromatography-mass spectrometry have been used to analyze these layers in samples from Sweden and some other European countries. The layers mainly consist of various iron oxides and iron oxide hydroxides, sulphates, soot and silicate minerals, with smaller amounts of metal, rubber and asphalt particles, and numerous organic constituents in low concentration. Air pollutants, and to some degree minerals from the interior of the stone, are the main source of the components which form the black layers.