Confusion approach to porphyrinoid chemistry.
Confusion approach to porphyrinoid chemistry.
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DOI：
10.1021/ar0302686
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发表时间：
2005
影响因子：
18.3
通讯作者：
A. Srinivasan;H. Furuta
中科院分区：
文献类型：
--
作者：
A. Srinivasan;H. Furuta
氮杂卟啉（NCP）是一种与母体卟啉在物理、化学、结构和配位性质上有很大不同的卟啉异构体。在正常卟啉和膨胀卟啉中引入混乱吡咯，可生成结构多样性丰富的混乱卟啉类化合物。本文介绍了近年来合成的一系列氮杂卟啉类化合物，并着重介绍了它们的性质，如稠合、外围氮配位、超分子组装、阴离子结合和单线态氧敏化等。
N-confused porphyrin (NCP) is a porphyrin isomer that is different largely from the parent porphyrin, particularly in the physical, chemical, structural, and coordination properties. Introduction of the confused pyrrole into the normal and expanded porphyrins leads to generation of the confused porphyrinoids having rich structural diversity. In this Account, we introduce a series of N-confused porphyrinoids recently synthesized and highlight their properties such as fusion, peripheral N coordination, supramolecular assemblies, anion binding, and singlet-oxygen sensitization.