Too many rearrangements of cyclohexadienones

Too many rearrangements of cyclohexadienones
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DOI:
10.1021/ar50091a005
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发表时间:
1975-07
影响因子:
18.3
通讯作者:
B. Miller
B. Miller
中科院分区:
化学1区
文献类型:
--
作者:
B. Miller

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The investigations described above amply illus-trate an important influence of ionic association upon orientation and stereochemistry in base-promoted ß elimination. Dependence of these effects upon the charge type of the leaving group is underscored. Recognition of these factors will provide new mecha-nistic insight into base-induced^-elimination reac-tions and may lead to improved reagents for alkene synthesis.