Boron in Disguise: The Parent "Fused" BN Indole
Boron in Disguise: The Parent "Fused" BN Indole
复制标题
DOI：
10.1021/ja205779b
复制
发表时间：
2011-08-03
影响因子：
15
通讯作者：
Liu, Shih-Yuan
中科院分区：
文献类型：
--
作者：
Abbey, Eric R.;Zakharov, Lev N.;Liu, Shih-Yuan
"稠合" BN吲哚是一类新兴的含硼吲哚模拟物，具有与吲哚类似的几何结构和亲电芳香取代反应性，但表现出独特的电子结构，导致独特的光电性能。在本文中，我们报告了母体N-H BN吲哚的合成，并提供了这种混合有机/无机吲哚与经典天然吲哚的结构特征、pK（a）值和光电性质的头对头比较。
"Fused" BN indoles are an emerging class of boron-containing indole mimics, featuring geometric structure and electophilic aromatic substitution reactivity similar to those of indoles but exhibiting distinct electronic structure, leading to unique optoelectronic properties. Herein we report the synthesis of the parent N-H BN indole and provide a head-to-head comparison of the structural features, pK(a) values, and optoelectronic properties of this hybrid organic/inorganic indole with the classic natural indole.