Elusive Scorpionates: C3-Symmetric, Formally Dianionic, Facially Tridentate Ligands.
Elusive Scorpionates: C3-Symmetric, Formally Dianionic, Facially Tridentate Ligands.
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难以捉摸的蝎形配体：C3 对称、形式双阴离子、表面三齿配体。
DOI：
10.1021/acs.inorgchem.7b02884
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发表时间：
2018
影响因子：
4.6
通讯作者：
Lan‐Chang Liang
中科院分区：
文献类型：
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作者：
Wei;Lan‐Chang Liang
AlCl 3与[（2-HO-3，5-tBu 2C 6 H2）3 P]（H3[O3 P]）反应生成AlCl[O3 PH]（[O3 PH]2- = [（2-O-3，5-tBu 2C 6 H2）3 PH]2-），其为两性离子分子，含有前所未有的C3对称但形式上双阴离子螯合物。[O3 PH]2-衍生得到[O3 PR]2-（R =烃），证明了一类新的长的难以捉摸的蝎子的发展。
The reaction of AlCl3 with [(2-HO-3,5-tBu2C6H2)3P] (H3[O3P]) results in AlCl[O3PH] ([O3PH]2- = [(2-O-3,5-tBu2C6H2)3PH]2-), which is a zwitterionic molecule containing an unprecedented C3-symmetric but formally dianionic chelate. Derivatization of [O3PH]2- gives [O3PR]2- (R = hydrocarbon), demonstrating the development of a novel class of long elusive scorpionates.