Front Cover: Mechanistic Study of Domino Processes Involving the Bidentate Lewis Acid Catalyzed Inverse Electron‐Demand Diels−Alder Reaction (28/2021)
Front Cover: Mechanistic Study of Domino Processes Involving the Bidentate Lewis Acid Catalyzed Inverse Electron‐Demand Diels−Alder Reaction (28/2021)
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封面：涉及双齿路易斯酸催化逆电子-需求狄尔斯-阿尔德反应的多米诺骨牌过程的机理研究 (28/2021)
DOI：
10.1002/ejoc.202100732
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发表时间：
2021
影响因子：
2.8
通讯作者：
H. A. Wegner
中科院分区：
文献类型：
--
作者：
M. A. Strauss;D. Kohrs;J. Ruhl;H. A. Wegner
封面显示了来自关键的双齿BN络合物的不同反应路径的示意图。所描述的产物是反电子需求Diels-Alder(IEDDA)反应的结果，随后是高温消除、过量胺介导的基团转移反应或光诱导开环反应的结果。在这项机理研究中，我们对多米诺骨牌IEDDA反应有了更深入的了解。背景描绘了奥地利的‘Plansee’湖(版权归Julia Ruhl所有)，其邻近的山口让人想起典型的势能面描绘(插图版权归Marcel A.Strauss所有)。更多信息可在HA Wegner等人的全文中找到。
The Front Cover shows a schematic presentation of different reaction pathways from a key bidentate BN complex. The depicted products are a result of an inverse electron demand Diels-Alder (IEDDA) reaction followed by either an elimination at high temperatures, a group-transfer reaction mediated by excess amine, or a photo-induced ring opening reaction. Within this mechanistic study, deeper insights into domino IEDDA reactions were gained. The background portrays the lake ‘Plansee’in Austria (copyright by Julia Ruhl), whose neighbored mountain pass reminds of a typical depiction of a potential energy surface (copyright of the illustration by Marcel A. Strauss). More information can be found in the Full Paper by HA Wegner et al.