Four different emissions from a Pt(Bodipy)(PEt3)2(S-Pyrene) dyad.
Four different emissions from a Pt(Bodipy)(PEt3)2(S-Pyrene) dyad.
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DOI：
10.1039/c8dt04823a
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发表时间：
2019-01
影响因子：
4
通讯作者：
P. Irmler;Franciska S. Gogesch;Christopher B. Larsen;O. Wenger;R. Winter
中科院分区：
文献类型：
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作者：
P. Irmler;Franciska S. Gogesch;Christopher B. Larsen;O. Wenger;R. Winter
铂(BODIPY)-(硫代吡喃)二聚体BPtSPyr表现出四种不同的发射：来自电荷转移态PYRS·+-铂-BDP·-的强烈近红外磷光(ΦpH高达15%)，来自BODIPY配体的1ππ*和3ππ*态的额外的荧光和磷光发射，以及77K时玻璃基质中Py的3ππ*和BODIPY 3ππ*态的磷光。
The Pt(bodipy)-(mercaptopyrene) dyad BPtSPyr shows four different emissions: intense near-infrared phosphorescence (Φph up to 15%) from a charge-transfer state pyrS˙+-Pt-BDP˙-, additional fluorescence and phosphorescence emissions from the 1ππ* and 3ππ* states of the bodipy ligand at r.t., and phosphorescence from the pyrene 3ππ* and the bodipy 3ππ* states in a glassy matrix at 77 K.