Polymerisation of a Cu(II) dimer into 1D chains using high pressure
Polymerisation of a Cu(II) dimer into 1D chains using high pressure
复制标题
使用高压将 Cu(II) 二聚体聚合成一维链
DOI：
10.1039/b912707k
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发表时间：
2009
期刊：
影响因子：
3.1
通讯作者：
S. Parsons
中科院分区：
文献类型：
--
作者：
S. Moggach;Kyle W. Galloway;A. Lennie;P. Parois;Niall Rowantree;E. Brechin;J. Warren;M. Murrie;S. Parsons
Long intermolecular interactions are converted into covalent bonds when the complex [Cu2(OH)(citrate)(Guanidine)2]− is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again.
