USING CSP TO UNDERSTAND COMPLEX CHEMICAL-KINETICS

USING CSP TO UNDERSTAND COMPLEX CHEMICAL-KINETICS
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DOI:
10.1080/00102209308924120
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发表时间:
1993-01-01
影响因子:
1.9
通讯作者:
LAM, SH
LAM, SH
中科院分区:
工程技术4区
文献类型:
--
作者:
LAM, SH

文献摘要

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通过使用部分平衡和准稳态近似简化动力学建模的传统方法进行了审查和批评。计算奇异摄动(CSP)的方法,然后提出特别强调CSP数据的解释,以获得大规模复杂反应系统的物理见解。一个简单的例子是用来演示CSP如何处理复杂的化学动力学问题,没有直觉和经验的好处。
The conventional methods of simplified kinetics modeling through the use of partial-equilibrium and quasi-steady approximations are reviewed and critiqued. The method of computational singular perturbation (CSP) is then presented with special emphasis on the interpretation of CSP data to obtain physical insights on massively complex reaction systems. A simple example is used to demonstrate how CSP deals with complex chemical kinetics problems without the benefits of intuition and experience.