Bioinspired and Bioderived Aqueous Electrocatalysis.
Bioinspired and Bioderived Aqueous Electrocatalysis.
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DOI：
10.1021/acs.chemrev.2c00429
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发表时间：
2023-03-08
期刊：
影响因子：
62.1
通讯作者：
Titirici, Maria-Magdalena
中科院分区：
文献类型：
--
作者：
Barrio, Jesus;Pedersen, Angus;Favero, Silvia;Luo, Hui;Wang, Mengnan;Sarma, Saurav Ch.;Feng, Jingyu;Ngoc, Linh Tran Thi;Kellner, Simon;Li, Alain You;Sobrido, Ana Belen Jorge;Titirici, Maria-Magdalena
开发能够提供清洁能源燃料和化学品的高效和可持续的电化学系统是材料科学和工程当前面临的主要挑战之一。在过去的几十年里，在开发用于不同反应的强大电催化剂方面取得了重大进展，并从计算和实验工作中获得了基本见解。文献中一些最有前途的系统是基于昂贵和稀缺的铂族金属;然而，天然酶显示出最高的单位点催化活性，而它们的活性位点完全基于地球上丰富的金属。此外，天然生物质为生产具有多孔分级结构的先进碳质材料提供了有价值的原料。利用自然界的资源和设计灵感可以帮助创造更具可持续性和成本效益的策略，以制造具有成本效益，可持续和耐用的电化学材料和设备。这篇综述涵盖了从材料到设备工程的各个方面;我们首先讨论了具有生物启发功能（如酶活性位点）的碳基材料的设计，利用生物质资源构建定制的碳材料，以及它们在水分解，氧还原和CO2还原的水电催化中的活性。然后，我们深入研究了生物启发功能在电化学设备中的适用性，例如生物启发质量传输和电极界面的工程。最后，我们将解决剩余的挑战，例如生物启发活性位点的稳定性或无金属碳材料的活性，并讨论新的潜在研究方向，这些方向可以打开在电化学设备中实施生物启发可持续材料的大门。
The development of efficient and sustainable electrochemical systems able to provide clean-energy fuels and chemicals is one of the main current challenges of materials science and engineering. Over the last decades, significant advances have been made in the development of robust electrocatalysts for different reactions, with fundamental insights from both computational and experimental work. Some of the most promising systems in the literature are based on expensive and scarce platinum-group metals; however, natural enzymes show the highest per-site catalytic activities, while their active sites are based exclusively on earth-abundant metals. Additionally, natural biomass provides a valuable feedstock for producing advanced carbonaceous materials with porous hierarchical structures. Utilizing resources and design inspiration from nature can help create more sustainable and cost-effective strategies for manufacturing cost-effective, sustainable, and robust electrochemical materials and devices. This review spans from materials to device engineering; we initially discuss the design of carbon-based materials with bioinspired features (such as enzyme active sites), the utilization of biomass resources to construct tailored carbon materials, and their activity in aqueous electrocatalysis for water splitting, oxygen reduction, and CO2 reduction. We then delve in the applicability of bioinspired features in electrochemical devices, such as the engineering of bioinspired mass transport and electrode interfaces. Finally, we address remaining challenges, such as the stability of bioinspired active sites or the activity of metal-free carbon materials, and discuss new potential research directions that can open the gates to the implementation of bioinspired sustainable materials in electrochemical devices.
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影响因子：
8
作者：
Bae G;Kim H;Choi H;Jeong P;Kim DH;Kwon HC;Lee KS;Choi M;Oh HS;Jaouen F;Choi CH
通讯作者：
Choi CH
影响因子：
18
作者：
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通讯作者：
Barber, James
影响因子：
12.9
作者：
Akbashev, Andrew R.
通讯作者：
Akbashev, Andrew R.
影响因子：
22
作者：
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通讯作者：
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影响因子：
29.4
作者：
Barthlott, Wilhelm;Schimmel, Thomas;Bohn, Holger F.
通讯作者：
Bohn, Holger F.