Haupt magnetic double resonance
Haupt magnetic double resonance
复制标题
豪普特磁双共振
DOI:
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发表时间:
2003
期刊:
影响因子:
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通讯作者:
B. Meier
中科院分区:
文献类型:
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作者:
M. Tomaselli;C. Degen;B. Meier
The coupling of the tunneling- and proton dipolar reservoirs of a weakly hindered methyl group is used to dynamically polarize the rare-spin nuclei by combination with suitable radio-frequency irradiation schemes. 1H→13C and 1H→15N double-resonance experiments below 60 K in a pure γ-picoline matrix and with 1.5 % 15N-acetonitrile as a guest are reported at a field of 5.17 Tesla.