Electro-Copolymerization of Poly(N-Vinylcarbazole) and 3-Methylthiophene
Electro-Copolymerization of Poly(N-Vinylcarbazole) and 3-Methylthiophene
复制标题
DOI：
10.4028/www.scientific.net/amr.800.531
复制
发表时间：
2013-09
期刊：
影响因子：
--
通讯作者：
S. Zhang;Ruirui Yue;Wei Zhou;Jingkun Xu
中科院分区：
文献类型：
--
作者：
S. Zhang;Ruirui Yue;Wei Zhou;Jingkun Xu
在含有10%三氟化硼乙醚（BFEE）（体积）和Bu4NBF4 （0.05 M）的二氯甲烷中，通过直接阳极氧化单体混合物，成功地实现了聚（n -乙烯基咔唑）（PVK）和3-甲基噻吩（3MeT）的电化学共聚。用红外光谱对共聚物的结构进行了表征。荧光光谱研究表明，聚（PVK-co-3MeT）具有较高的荧光性能，其最大发射波长在410 nm附近。
The electrochemical copolymerization of poly (N-vinylcarbazole) (PVK) and 3-methylthiophene (3MeT) was successfully achieved by direct anodic oxidation of monomer mixtures in dichloromethane containing 10% boron trifluoride diethyl etherate (BFEE) (by volume) and Bu4NBF4 (0.05 M). The structure of the copolymer was characterized by infrared spectroscopy. Fluorescence spectral studies demonstrated that poly (PVK-co-3MeT) has high fluorescent property with its maximum emission at near 410 nm.