Synthesis and properties of bitetraselenafulvalene
Synthesis and properties of bitetraselenafulvalene
复制标题
DOI：
10.1016/s0040-4039(99)01085-0
复制
发表时间：
1999-07-30
影响因子：
1.8
通讯作者：
Otsubo, T
中科院分区：
文献类型：
--
作者：
Iyoda, M;Hara, K;Otsubo, T
铜(II)和钯(II)催化的三甲基锡基四硒富瓦烯的原位偶联反应顺利进行，以较高的产率合成了双硒富瓦烯(BiTSF)。对BiTSF进行了X射线分析，发现了一种有趣的晶体结构。从biTSF衍生的CT-络合物和自由基阳离子盐显示出相当高的电导率。(C)1999爱思唯尔科学有限公司。保留所有权利。
Copper(II)- and palladium(II)-catalyzed home-coupling reactions of trimethylstannyltetraselenafulvalene proceed smoothly to produce bitetraselenafulvalene (biTSF) in good yield. The X-ray analysis of biTSF shows an interesting crystal structure. The CT-complex and radical cation salts derived from biTSF indicate fairly high electric conductivities. (C) 1999 Elsevier Science Ltd. All rights reserved.