Heterocycle Formation from Zirconacycles
Heterocycle Formation from Zirconacycles
复制标题
DOI：
10.1002/chin.200914236
复制
发表时间：
2008-11
期刊：
影响因子：
--
通讯作者：
Lishan Zhou;Masamichi Yamanaka;K. Kanno;Tamotsu Takahashi
中科院分区：
文献类型：
--
作者：
Lishan Zhou;Masamichi Yamanaka;K. Kanno;Tamotsu Takahashi
综述了锆介导的一系列杂环化合物的合成方法。讨论的重点是包括其他金属的反应，如铜、镍、锂等。这些使我们能够合成一系列环骨架中含有N、O、Si、S、Sn等的杂环。该反应的关键是从Zr到其他所用金属的金属转移，这对于反应的反应活性和选择性起着至关重要的作用。
Zirconium-mediated synthetic methods of a series of heterocyclic compounds were reviewed. Discussion was focused on the reactions including the other metals, such as Cu, Ni, Li, and so on. These enable us to synthesize a series of heterocycles having N, O, Si, S, Sn, etc. in the ring skeletons. The key point of the reaction is transmetalation from Zr to the other employed metals, which have a crucial role for reactivity and selectivity of the reaction.