Palladium-Catalyzed C-S Coupling: Access to Thioethers, Benzo[b]thiophenes, and Thieno[3,2-b]thiophenes
Palladium-Catalyzed C-S Coupling: Access to Thioethers, Benzo[b]thiophenes, and Thieno[3,2-b]thiophenes
复制标题
DOI：
10.1021/ol2016093
复制
发表时间：
2011-08-05
期刊：
影响因子：
5.2
通讯作者：
Paradies, Jan
中科院分区：
文献类型：
--
作者：
Kuhn, Marius;Falk, Florian C.;Paradies, Jan
首次开发了以硫脲作为廉价易操作的二氢硫化物替代物的C-S键形成/交叉偶联/环化多米诺反应。以高产率提供结构上重要的联芳基硫醚、苯并[B]噻吩和噻吩并[3，2-B]噻吩骨架。
The first C-S bond formation/cross-coupling/cyclization domino reaction using thiourea as a cheap and easy to handle dihydrosulfide surrogate has been developed. Structurally Important biarylthioether, benzo[b]thiophenes, and thieno[3,2-b]thiophene scaffolds are provided in high yield.