Electroreductive coupling of organic halides in alcoholic solvents. An example: The electrosynthesis of biaryls catalysed by nickel-2,2' bipyridine complexes.
Electroreductive coupling of organic halides in alcoholic solvents. An example: The electrosynthesis of biaryls catalysed by nickel-2,2' bipyridine complexes.
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DOI：
10.1016/s0040-4020(97)00744-8
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发表时间：
1997-08-25
期刊：
影响因子：
2.1
通讯作者：
Perichon, J
中科院分区：
文献类型：
--
作者：
Courtois, V;Barhdadi, R;Perichon, J
醇如甲醇或乙醇是根据涉及镍-2,2'-联吡啶络合物催化的程序实现从芳基卤化物电合成联芳基的合适溶剂。所有电解均在配有铁或硬铝牺牲阳极的不分隔电解槽中以恒定电流进行。 (C) 1997 爱思唯尔科学有限公司。
Alcohols like methanol or ethanol are suitable solvents for achieving the electrosynthesis of biaryls from aryl halides according to a procedure which involves a catalysis by nickel-2,2'-bipyridine complexes. All electrolyses were carried out at constant current in an undivided cell fitted with an iron or duralumin sacrificial anode. (C) 1997 Elsevier Science Ltd.