CIRCULAR-DICHROISM OF COBALT(III) COMPLEXES .2. PHASE-CHANGES IN LAMBDA-CO(SEP)(NO3)3
CIRCULAR-DICHROISM OF COBALT(III) COMPLEXES .2. PHASE-CHANGES IN LAMBDA-CO(SEP)(NO3)3
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DOI：
10.1021/j150663a014
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发表时间：
1984-01-01
影响因子：
--
通讯作者：
WILLIAMSON, B
中科院分区：
文献类型：
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作者：
DUBICKI, L;FERGUSON, J;WILLIAMSON, B
‘A！过渡。氢键硝酸根离子在降低295K的转动强度以及产生很大的温度依赖性方面的影响已经在其他地方被描述过。外球硝酸根离子也是质子化和氚化络合物结构相变的原因。用光学结晶学、单晶拉曼光谱和圆二色谱确定了结构相的微观和宏观性质。
‘A! transition. The influence of the H-bonded nitrate ions in reducingthe rotatory strengthat 295 K, as well as producing a large temperature dependence, has been described elsewhere. The outer sphere nitrate ions are also responsible for structural phase changes in both the protonated and deuterated complexes. Optical crystallography, single-crystal Raman, and CD spectra have been used to establish the microscopic and macroscopic nature of the structural phases.