The temperature dependent, infrared absorption cross-sections for the chlorofluorocarbons: CFC-11, CFC-12, CFC-13, CFC-14, CFC-22, CFC-113, CFC-114, and CFC-115

The temperature dependent, infrared absorption cross-sections for the chlorofluorocarbons: CFC-11, CFC-12, CFC-13, CFC-14, CFC-22, CFC-113, CFC-114, and CFC-115
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含氯氟烃的温度依赖性红外吸收截面:CFC-11、CFC-12、CFC-13、CFC-14、CFC-22、CFC-113、CFC-114 和 CFC-115

DOI:
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发表时间:
1991
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影响因子:
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通讯作者:
J. Calvert
J. Calvert
中科院分区:
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文献类型:
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作者:
A. McDaniel;C. Cantrell;J. A. Davidson;R. Shetter;J. Calvert

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本文测量了八种常用卤代甲烷和乙烷在203~293K温度范围内的红外吸收截面,并用高分辨光谱(0.03 cm~(-1))求出了600~1500 cm~(-2)红外光谱特征的积分谱带强度和峰截面。将本研究中获得的值与以前的报告中的值进行了比较,并提出了在大气传感和辐射能量转移模型中使用的建议。文中还讨论了光谱特征中观测到的温度依赖性。
The infrared absorption cross-sections for eight commonly used halogenated methanes and ethanes have been measured as a function of temperature from 203 to 293 K. High resolution spectra (0.03 cm-1) have been used to derive integrated band strengths and peak cross-sections associated with the spectral features in the infrared region from 600 to 1500 cm-2. The values obtained in this study are compared to those from previous reports, and recommendations are made for uses in atmospheric sensing and radiative energy transfer models. The observed temperature dependence in the spectral features is also discussed.