"Electro-photo switch" and "molecular light switch" devices based on ruthenium(II) complexes of modified dipyridophenazine ligands: Modulation of the photochemical function through ligand design

"Electro-photo switch" and "molecular light switch" devices based on ruthenium(II) complexes of modified dipyridophenazine ligands: Modulation of the photochemical function through ligand design
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DOI:
10.1021/ic981109z
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发表时间:
1999-03-08
影响因子:
4.6
通讯作者:
Maiya, BG
Maiya, BG
中科院分区:
化学2区
文献类型:
--
作者:
Arounaguiri, S;Maiya, BG

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[Ru(phen)2(qdppz)]2+和[Ru(phen)2(dicnq)]2+都表现出有趣的光化学性质,这取决于它们中配位的dipidophenazine基配体的特征:前一种配合物作为“光电开关”,后者已被证明是DNA的“分子光开关”。
Both [Ru(phen)2(qdppz)]2+and [Ru(phen)2(dicnq)]2+exhibit interesting photochemical properties depending on the characteristic features of the coordinated dipyridophenazine-based ligand in them:  while the former complex acts as an “electro-photo switch”, the latter one has been demonstrated to be a “molecular light switch” for DNA.