Reconciling icetexane biosynthetic connections with their chemical synthesis:: Total synthesis of (±)-5,6-dihydro-6α-hydroxysalviasperanol, (±)-brussonol, and (±)-abrotanone
Reconciling icetexane biosynthetic connections with their chemical synthesis:: Total synthesis of (±)-5,6-dihydro-6α-hydroxysalviasperanol, (±)-brussonol, and (±)-abrotanone
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DOI：
10.1021/ol0712428
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发表时间：
2007-07-05
期刊：
影响因子：
5.2
通讯作者：
Sarpong, Richmond
中科院分区：
文献类型：
--
作者：
Simmons, Eric M.;Yen, Jennifer R.;Sarpong, Richmond
一个统一的策略，化学合成冰己烷二萜类brussonol和5,6-二氢-6 α -羟基蛇柳木醇导致结构修正最近分离的天然产物abrotanol和abrotanone。
A unified strategy for the chemical synthesis of the icetexane diterpenoids brussonol and 5,6-dihydro-6 alpha-hydroxysalviasperanol has led to a structural revision of the recently isolated natural products abrotandiol and abrotanone.